| Title | Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C-60-Br bond |
| Authors | Jia, Zhenshan Zhang, Qianyan Li, Yuliang Gan, Liangbing Zheng, Bo Yuan, Gu Zhang, Shiwei Zhu, Daoben |
| Affiliation | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100080, Peoples R China. Peking Univ, Coll Chem & Mol Engn, Minist Educ Res, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China. |
| Keywords | fullerene halogenation homolysis heterolysis alkoxylation FULLERENE MIXED PEROXIDES NUCLEOPHILIC-SUBSTITUTION DERIVATIVES CATION FUNCTIONALIZATION <60>FULLERENE REACTIVITY CHEMISTRY |
| Issue Date | 2007 |
| Publisher | tetrahedron |
| Citation | TETRAHEDRON.2007,63,(37),9120-9123. |
| Abstract | The bromine atom in a fullerene-mixed peroxide derivative is replaced by an alkoxyl group under visible light irradiation or in the presence of silver salt. Homolytic or heterolytic cleavage of the C-60-Br bond is proposed to explain the mechanism. The presence of oxygen is also a key factor in the photolysis reaction. (c) 2007 Elsevier Ltd. All rights reserved. |
| URI | http://hdl.handle.net/20.500.11897/249701 |
| ISSN | 0040-4020 |
| DOI | 10.1016/j.tet.2007.06.070 |
| Indexed | SCI(E) |
| Appears in Collections: | 化学与分子工程学院 生物有机与分子工程教育部重点实验室 |
