| Title | Preparation of covalent-bound iodofullerene through selective opening of fullerene epoxide to form halohydrin fullerene derivatives |
| Authors | Huang, Shaohua Yang, Xiaobing Zhang, Xiang Hu, Xiangqing Gan, Liangbing Zhang, Shiwei |
| Affiliation | Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China. Beijing Inst Pharmaceut Chem, Beijing 100083, Peoples R China. Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China. State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China. |
| Keywords | fullerene halohydrin epoxides peroxide Lewis acid MIXED PEROXIDES IODINE C-60 |
| Issue Date | 2006 |
| Publisher | synlett |
| Citation | SYNLETT.2006,(8),1266-1268. |
| Abstract | The epoxy moiety in a fullerene mixed peroxide can be opened regioselectively by various Lewis acids to form halohydrin fullerene derivatives. The first iodofullerene was obtained by treating the fullerene epoxide with triphenylphosphine and iodine. A single-crystal structure of the chlorohydrin derivative supports the results. |
| URI | http://hdl.handle.net/20.500.11897/398666 |
| ISSN | 0936-5214 |
| DOI | 10.1055/s-2006-932462 |
| Indexed | SCI(E) |
| Appears in Collections: | 化学与分子工程学院 生物有机与分子工程教育部重点实验室 |
