| Title | 三维配位聚合物[Sr(BDC)(H2O)]的合成,结构与热稳定性 |
| Other Titles | Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H2O)] |
| Authors | 付颖 李国宝 廖复辉 林建华 |
| Affiliation | 北京分子科学国家实验室,稀土材料化学与应用国家重点实验室,北京大学化学与分子工程学院,北京100871 |
| Keywords | 1,4-对苯二甲酸 锶 溶剂热合成 结构 热稳定性 1,4-Benzenedicarboxylic acid Strontium Solvothermal synthesis Structure Thermal property |
| Issue Date | 2011 |
| Publisher | 物理化学学报 |
| Citation | 物理化学学报.2011,27,(10),2269-2274. |
| Abstract | 利用溶剂热法在硝酸锶、1,4-对苯二甲酸(BDC)、N,N′-二甲基甲酰胺(DMF)和水体系中合成了一种新的配位聚合物[Sr(BDC)(H2O)] (1),并通过单晶X射线衍射、变温粉末X射线衍射、元素分析、红外光谱和热重-质谱联用对其进行了表征.该化合物属正交晶系的Pbca空间群,晶胞参数为a=1.1854(2) nm,b--0.7122(1) nm,c=2.0031(4) nm.该化合物具有三维网络结构,由共面的SrO8四方反棱柱组成的zigzag链通过1,4-对苯二甲酸配体连接而成.热重-质谱联用和变温粉末X射线衍射分析表明它的骨架具有较高的热稳定性. The solvothermal reactions of Sr(NO3)(2) with 1,4-benzenedicarboxylic acid (BDC) in a mixture of H2O/N,N'-dimethylformamide (DMF) resulted in a novel coordination polymer, [Sr(BDC) (H2O)] (1), which was characterized by single crystal and variable temperature powder X-ray diffraction (VTPXRD), elemental analysis, infra-red (IR) spectroscopy, and thermogravimetric-mass spectrometric (TG-MS) analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with a=1.1854(2) nm, b=0.7122 (1) nm, and c=2.0031(4) nm. It is a three-dimensional (3D) framework consisting of zigzag chains that are formed by face-shared SrO8 square antiprisms and bridging BDC ligands. TG-MS and VTPXRD studies revealed that the framework of compound 1 exhibited a high thermal stability. |
| URI | http://hdl.handle.net/20.500.11897/80067 |
| ISSN | 1000-6818 |
| DOI | 10.3866/PKU.WHXB20110908 |
| Indexed | SCI(E) 中文核心期刊要目总览(PKU) 中国科技核心期刊(ISTIC) 中国科学引文数据库(CSCD) |
| Appears in Collections: | 化学与分子工程学院 稀土材料化学与应用国家重点实验室 |
