| Title | 钠盐修饰的Mn/SiO2催化剂的原位XRD研究 |
| Other Titles | In Situ XRD Study on Sodium Salt-Modified Mn/SiO2 Catalysts for the Oxidative Coupling of Methane |
| Authors | 侯思聪 曹元 熊伟 刘凌涛 寇元 |
| Affiliation | 北京大学化学与分子工程学院分子动态与稳态结构国家重点实验室,北京100871 |
| Keywords | 钠盐 氧化锰 二氧化硅 原位X射线衍射 低熔点 无定形 甲烷氧化偶联 sodium salt manganese oxide silica in situ X-ray diffraction low melting point amorphous oxidative coupling of methane |
| Issue Date | 2006 |
| Publisher | 催化学报 |
| Citation | 催化学报.2006,27,(7),553-555. |
| Abstract | 采用原位X射线衍射法对高温下不同钠盐修饰的Mn/SiO2催化剂物相结构进行了研究.结果表明,反应温度下催化剂表面的钠盐处于熔融的无定形态,提高了Mn2O3活性中心在甲烷氧化偶联反应中的催化活性. Sodium salt-modified Mn/SiO2 catalysts have been characterized by in situ X-ray diffraction. The results indicate that the low melting point sodium salts exhibit amorphous features under reaction conditions and they are good promoters for the Mn/SiO2 catalyst for the oxidative coupling of methane. |
| URI | http://hdl.handle.net/20.500.11897/80502 |
| ISSN | 0253-9837 |
| DOI | 10.3321/j.issn:0253-9837.2006.07.005 |
| Indexed | SCI(E) 中文核心期刊要目总览(PKU) 中国科技核心期刊(ISTIC) 中国科学引文数据库(CSCD) |
| Appears in Collections: | 化学与分子工程学院 |
